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Beilstein J. Org. Chem. 2021, 17, 1591–1599, doi:10.3762/bjoc.17.113
Graphical Abstract
Figure 1: Assembly of 3-methyleneisoindolin-1-one via 3d transition metal-mediated/catalyzed oxidative C−H/N−...
Scheme 1: Copper-mediated oxidative C−H/N−H functionalization of hydrazides 1 with ethynylbenzene (2a).
Scheme 2: Copper-mediated oxidative C−H/N−H functionalization of 1 with alkynes 2.
Scheme 3: Decaboxylative C−H/N−H activation and cleavage of the directing group.
Scheme 4: Summary of key mechanistic findings.
Scheme 5: Proposed reaction pathway.
Beilstein J. Org. Chem. 2019, 15, 1203–1209, doi:10.3762/bjoc.15.117
Scheme 1: Synthetic route of perylene- and naphthalene-crown macrocycle conjugates 1 and 2.
Figure 1: (a) UV–vis absorption spectra and (b) fluorescence spectra (λex = 490 nm) of 1 in different solvent...
Figure 2: TEM images of 1 aggregates in (a) CHCl3, (b) MeCN, and (c) H2O/MeCN (v/v = 10:1) (inset: schematic ...